Micromorphological Characteristics of Polluted Soils in Tehran Petroleum Refinery

Authors
Department of Soil Science, Faculty of Agricultural Engineering and Technology, University of Tehran, Karaj, Islamic Republic of Iran.
Abstract
In this study, micromorphological properties of some samples collected from pedons polluted with petroleum refinery wastes and some adjacent unpolluted pedons were studied. After description of the studied pedons, disturbed and undisturbed samples were collected for physicochemical and micromorphological analyses. The results showed that the physicochemical properties (i.e. structure, bulk density, pH, EC and organic matter) of the soils polluted with petroleum wastes were strongly changed. Prolonged exposure of soils to the petroleum wastes resulted in the formation of specific and distinctive micromorphological features. Strongly developed granular microstructure and infillings of solid petroleum wastes alone or mixed with soil aggregates were some of the most important pedofeatures which were observed in deeper horizons. The existence of excrement belonging to different soil micro and macro fauna, coatings, hypocoatings, quasicoatings, and zones depleted from petroleum dissolvable materials at different depths were the other features throughout the pedons. The type of developed pedofeatures was correlated with the state of petroleum wastes and their fluidity in penetration, deposition, or dissolving and removal of soil compounds. This study demonstrated that micromorphology can be used as a powerful technique in characterization of petroleum polluted soils.

Keywords


1. Asadi, P. and Heidari, A. 2012. Mineralogical and Physicochemical Properties of Some Oil Polluted Soils. First National Conference for Guidelines Achieving Sustainable Development, Tehran, Iran.
2. Bowders, J. J., Daniel, D. E., Broderick, G. P. and Liljestrand, H. M. 1985. Methods for Testing the Compressibility of Clay Liners with Landfill Leachate. In: "Hazardous and Industrial Solid Waste Testing, Fourth Symposium", (Ed.): ASTM STP 886. American Society for Testing Materials, pp. 233–250.
3. FAO. 2014. World Reference Base for Soil Resources, International Soil Classification System for Naming Soils and Creating Legends for Soil Maps: World Soil Resources Reports No. 106. FAO, Rome.
4. Gee, G. W. and Bauder, J. W. 1986. Particle-Size Analysis. In: Methods of Soil Analysis. Part 1. "Physical and Mineralogical Methods", (Ed.): Klute, A.. American Society of Agronomy, PP. 383–411.
5. Gitipour, S., Nabi, Gh. and Gorji, M. A. 2004. Soils Contaminated by Leaking Petroleum Compounds in South of Tehran Refinery. J. Ecol., 34: 39-45.
6. Gulshan, A. B. and Dasti, A. A. 2012. Role of Soil Texture and Depths on the Emergence of Buried Weed Seeds. ARPN J. Agric. Biolog. Sci., 7: 223-228.
7. Heidari, A., Mahmoodi, Sh., Stoops, G. and Mees, F. 2005. Micromorphological Characteristics of Vertisols of Iran, Including Non-smectitic Soils, ALRM, 19: 29-46.
8. Heidarzadeh, N., Gitipour, S. and Abdoli, M. A. 2009. Statistical Sampling and Sludge Characterization at Tehran Oil Refinery. Res. J. Chem. Environ., 13(4).
9. Hesse, P.R. 1976. Particle Size Distribution in Gypsic Soils. Plant Soil, 44: 241-247.
10. Kaya, A. and Fang, H. Y. 2000. The Effects of Organic Fluids on Physicochemical Parameters of Fine-grained Soils. Can. Geotech. J., 37: 943–950.
11. Kaya, A. and Fang, H. Y. 2005. Experimental Evidence of Reduction in Attractive and Repulsive Forces between Clay Particles Permeated with Organic Fluids: Technical Note. Can. Geotech. J., 42: 632–640.
12. Khademi, H. and Mermut, A. R. 2003. Micromorphology and Classification of Argids and Associated Gypsiferous Aridisols from Central Iran. Catena, 54: 439–455.
13. Laurent, F., Cebron, A., Schwartz, C. and Leyval, C. 2012. Oxidation of a PAH Polluted Soil Using Modified Fenton Reaction in Unsaturated Condition Affects Biological and Physico-chemical Properties. Chemosphere, 86: 659–664.
14. Mesri, G. and Olson, R. E. 1971. Mechanisms Controlling the Permeability of Clays. Clay. Clay Mineral., 19(3): 151–158.
15. Mitchell, J. K. 1976. Fundamentals of Soil Behaviour. John Wiley, New York.
16. Nwazue, N. R. 2011. The Effect of Crude Oil Spill on the Ascorbic Acid Content of Some Selected Vegetable Species in an Oil Polluted Soil. Pak. J. Nutr., 10(3): 274-281.
17. Olalemi, A. S. and Arotupin, D. J. 2012. Effect of Refined Petroleum Products Contamination on Bacterial Population and Physicochemical Characteristics of Cultivated Agricultural Soil. J. Microbiol. Biotech. Food Sci., 2(2): 684-700.
18. Olgun, M. 2008. The Investigation of Shear Strength and Consolidation Behaviors of Clay Soils Consolidated with Chemicals of Various Concentrations. PhD. Thesis, Selcuk University, Konya.
19. Onojake, M. C. and Osuji, L. C. 2012. Assessment of the Physico-chemical Properties of Hydrocarbon Contaminated Soil. Arch. Appl. Sci. Res., 4(1): 48-58.
20. Pathak, H., Bhatnagar, K. and Jaroli, D. P. 2011. Physico-chemical Properties of Petroleum Polluted Soil Collected from Transport Nagar (Jaipur). IJ FALS, 1(3): 84-89.
21. Ratnaweera, P. and Meegoda, J. N. 2006. Shear Strength and Stress–strain Behaviour of Contaminated Soils. ASTM Geotech. Test. J., 29(2): 133–140.
22. Sawhney, B. L. 1996. The Connecticut Agricultural Experiment Station: New Haven, Connecticut, Extraction of Organic Chemical. Part 3. Chemical Methods. In: "Methods of Soil Analysis", (Eds.): Sparks, D. L., Page, A. L. Helmke, P. A. and Loeppert, R. H.. Soil Science Society of America, Inc. Madison, Wisconsin, USA, 1.
23. Soil Survey Staff. 2014. Keys to Soil Taxonomy. 12th Edition, USDA- NRCS.
24. Sparks, D. L. Page, A. L. Helmke, P. A. and Loeppert, R. H. 1996. Method of Soil Analysis. Part 3. Chemical Methods. American Society of Agronomy, Inc. Madison, Wisconsin, USA.
25. Stoops, G. 2003. Guidelines for the Analysis and Description of Soil and Regolith Thin Sections. SSSA, Madison, WI.
26. Stoops, G., Marcelino, V. and Mees, F., 2010. Interpretation of Micromorphological Features of Soils and Regoliths. Elsevier, Amsterdam, Netherlands.
27. USDA and NRCS. 2012. Java Newhall Simulation Model (JNSM 1.6.0). Available at: (http://soils.usda.gov/technical/classification/jNSM/index.html).
28. Walkley, A. and Black, I. A. 1934. An Examination of the Degtjareff Method for Determining Soil Organic Matter, and a Proposed Modification of the Chromic Acid Titration Method. Soil Sci., 34: 29-38.
29. Zand, D. A., Nabibidhendi, Gh., Mehrdadi, N., Shirdam, R. and Mikaeili Tabrizi A. 2010. Total Petroleum Hydrocarbon (TPHs) Dissipation through Rhizoremediation by Plant Species. Polish J. Environ. Stud., 19: 115-122.
30. Zhao, D. 1996. Experimental Study of Stress–strain and Shear Strength Behaviour of Contaminated Cohesive Soils. PhD. Dissertation, The Johns Hopkins University, Baltimore, Maryland.